A chiral ferromagnetic molecular metal.

نویسندگان

  • José R Galán-Mascarós
  • Eugenio Coronado
  • Paul A Goddard
  • John Singleton
  • Amalia I Coldea
  • John D Wallis
  • Simon J Coles
  • Antonio Alberola
چکیده

The first molecular material with the coexistence of ferromagnetism, metal-like conductivity, and chirality has been prepared using an organic/inorganic approach. In this case, a two-dimensional packing of chiral organic radical cations (responsible for both the electrical conductivity and optical activity) was assembled with a layered bimetallic oxalate-based anionic network (responsible for the magnetic properties). Shubnikov-de Haas oscillations confirmed the presence of a Fermi surface even when the transport properties suggested "insulating"-type behavior at very low temperatures.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 132 27  شماره 

صفحات  -

تاریخ انتشار 2010